Angelina Jolie and Brad Pitt Got Married in France Last Weekend Finally superstar couple Angelina Jolie and Brad Pitt were secretly married in France on Saturday, a spokesperson told the Associated Press on Thursday. The duo reportedly first came together on the set of Mr. and Mrs. Smith about a decade ago, but they were only engaged in 2012. Now, their marriage is official. Jolie and Pitt were married in Chateau Miraval in the south of France in a small ceremony attended by family and friends, including the couple’s six children, the AP reports. The couple is set to get back together on the screen next year in a drama that Jolie wrote and will direct called By the Sea, set for release next year.